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L23.4 Symmetric and Antisymmetric states of N particles

February 14, 2019
by
MIT OpenCourseWare
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L23.4 Symmetric and Antisymmetric states of N particles

TL;DR

Quantum mechanics introduces symmetric and anti-symmetric states that are eigenstates of permutation operators and help solve the problem of exchange degeneracy.

Transcript

PROFESSOR: With this, we can phase the construction of the operators that are going to help us build totally symmetric states and totally anti-symmetric states, and understand why we solve the problem of degeneracy, exchange degeneracy. So let us look into that. So this is called complete symmetrizers and anti-symmetrizers, complete symmetrizers an... Read More

Key Insights

  • 🦾 Permutation operators in quantum mechanics do not commute, making simultaneous diagonalization impossible.
  • 🇦🇬 Special states, such as symmetric and anti-symmetric states, can be found that are eigenstates of all permutation operators.
  • 🤘 Symmetric states are invariant under permutation operators, while anti-symmetric states change sign.
  • 🤙 Symmetric states form a subspace called symN(V), and anti-symmetric states form a subspace called antiN(V).
  • 👾 Projectors can be used to reach these subspaces, but they do not form a basis in the full Hilbert space.
  • 🤘 The sign factor, epsilon, ensures consistent sign changes for anti-symmetric states.

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Questions & Answers

Q: What is the significance of permutation operators in quantum mechanics?

Permutation operators in quantum mechanics represent the exchange of particles. They do not commute and cannot be simultaneously diagonalized.

Q: Can symmetric states in quantum mechanics form a basis in the full Hilbert space?

No, symmetric states cannot form a basis in the full Hilbert space because permutation operators do not commute. However, they can be reached by using projectors into a subspace of symmetric states.

Q: How are anti-symmetric states different from symmetric states?

Anti-symmetric states change sign under permutation operators. They are defined with a sign factor, epsilon, associated with each permutation. This solves the problem of inconsistent sign changes for multiple transpositions.

Q: What are the names given to the subspaces of symmetric and anti-symmetric states?

The subspace of symmetric states is called symN(V), representing symmetric states of N particles in space V. The subspace of anti-symmetric states is called antiN(V).

Summary & Key Takeaways

  • Permutation operators in quantum mechanics do not commute and cannot be simultaneously diagonalized.

  • However, it is possible to find special states that are eigenstates of all permutation operators.

  • Symmetric states are invariant under permutation operators and have eigenvalue 1, while anti-symmetric states change sign under permutation operators.


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