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Momentum operator, energy operator, and a differential equation

July 31, 2017
by
MIT OpenCourseWare
YouTube video player
Momentum operator, energy operator, and a differential equation

TL;DR

The lecture discusses the derivation of the Schrodinger equation, which describes the wave function for non-relativistic particles.

Transcript

PROFESSOR: Last time, we talked about the Broglie wavelength. And our conclusion was, at the end of the day, that we could write the plane wave that corresponded to a matter particle, with some momentum, p, and some energy, E. So that was our main result last time, the final form for the wave. So we had psi of x and t that was e to the i k x minus ... Read More

Key Insights

  • 🥶 The wave function for a free particle can be described by the Schrodinger equation.
  • 👋 The momentum operator reveals the momentum of the particle when acting on the wave function.
  • 👋 The energy operator captures the energy of the particle by acting on the wave function.
  • ❓ Eigenstates of operators represent states with definite momentum and energy.
  • 🉐 The momentum operator is defined as p hat = h bar/i * d/dx.
  • 😀 The energy operator is derived as -h^2/2m * d^2/dx^2.

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Questions & Answers

Q: What is the main objective of deriving the Schrodinger equation from the wave function?

The main objective is to establish a solid foundation for the wave function by finding an equation that describes the behavior of a free particle. Understanding the free particle case will then allow for generalization to particles under the influence of potentials.

Q: How can the momentum of a particle be determined from the wave function?

The momentum operator, denoted as p hat, acts on the wave function and yields the momentum as a result. Specifically, p hat = h bar/i * d/dx applied to psi gives the momentum times the wave function.

Q: What does it mean for a wave function to be an eigenstate of an operator?

If the action of an operator on a wave function produces the wave function multiplied by a number, then the wave function is an eigenstate of that operator. In this context, the psi of x and t is an eigenstate of the momentum operator.

Q: How is the energy of a particle determined from the wave function?

The energy operator, derived as p hat squared over 2m, acts on the wave function and yields the energy as a result. The energy operator is equivalent to -h^2/2m * d^2/dx^2 applied to psi.

Summary & Key Takeaways

  • The lecture begins by revisiting the Broglie wavelength and the wave function for a matter particle with momentum and energy.

  • The focus is on non-relativistic particles, and the equation E = p^2/2m is derived.

  • The concept of eigenstates and operators is introduced, and the momentum and energy operators are defined.

  • The momentum operator is found to be p hat = h bar/i * d/dx, and the energy operator is -h^2/2m * d^2/dx^2.

  • Finally, the Schrodinger equation is presented as i h bar d/dt * psi = E psi.


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