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9. Lewis Structures I (Intro to Solid-State Chemistry)

December 7, 2020
by
MIT OpenCourseWare
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9. Lewis Structures I (Intro to Solid-State Chemistry)

TL;DR

Lewis bonding involves ionic and covalent bonds, with electronegativity playing a role in determining the type of bond formed.

Transcript

OK, this is the thing. We've done a lot of work on ionic bonds. And I drew the ionic bond energy again, on Monday. And remember, in an ironic bond-- so let's take sodium chloride-- we have, oh, we're going to go Lewis, right? And people say, well, why did I draw that dot there. I could have drawn two dots there and that dot there. Sure. Yeah. But t... Read More

Key Insights

  • 🈂️ Ionic bonding involves a transfer of charges, while covalent bonding involves the sharing of electrons.
  • 🖐️ Electronegativity plays a role in determining the type of bond formed, with higher values indicating more ionic character.
  • 🈂️ Formal charge helps analyze the charge distribution in a molecule and can be used to determine the stability of a Lewis structure.
  • 🐻‍❄️ For bonds with electronegativity differences greater than 2, they tend to be ionic, while differences less than 1.6 tend to be covalent or polar covalent.

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Questions & Answers

Q: What is the difference between ionic and covalent bonding?

Ionic bonding occurs when one atom takes electrons from another, resulting in a transfer of charges. Covalent bonding occurs when atoms share electrons, resulting in a lower energy bond.

Q: What role does electronegativity play in bonding?

Electronegativity is a measure of an atom's tendency to attract shared electrons to itself. It determines the type of bond formed, with higher electronegativity leading to more ionic character and lower electronegativity leading to more covalent character.

Q: How are electrons shared in covalent bonds?

In covalent bonds, the electrons are shared between atoms. Each atom contributes an equal number of electrons to the bond, allowing them to fulfill their octet and form a stable bond.

Q: What is the significance of formal charge in Lewis structures?

Formal charge allows us to analyze the distribution of charge in a molecule. It is calculated by subtracting the number of lone pair and bonding electrons from the total valence electrons for an atom. The Lewis structure with formal charges closest to zero is usually the most stable.

Summary & Key Takeaways

  • Lewis bonding involves two types of bonds: ionic and covalent.

  • Ionic bonding occurs when one atom takes electrons from another, resulting in a transfer of charges.

  • Covalent bonding occurs when atoms share electrons, resulting in a lower energy bond.


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