Cyclohexanes: Crash Course Organic Chemistry #7 | Summary and Q&A

TL;DR

Hexagons, like those found in cyclohexane, are prevalent in the natural world due to their space-saving structure and stability.

Key Insights

• 👾 Hexagons are prevalent in nature due to their space-saving properties and structural stability.
• 😋 Cycloalkanes, including cyclohexane, are named based on the number and arrangement of substituents attached to the ring.
• 🌸 The chair conformation of cyclohexane is the most stable due to its low ring strain.
• 🧘 Substituents in cyclohexane prefer to be in the equatorial position to minimize steric hindrance and diaxial strain.
• 🧑‍🦼 Understanding the chair conformation of cyclohexane is important in organic chemistry as it affects the function and properties of molecules.
• 😋 Combustion reactions and bomb calorimetry can be used to quantify ring strain in cycloalkanes.

Transcript

You can review content from Crash Course Organic Chemistry with the Crash Course app, available now for Android and iOS devices. Hi! I’m Deboki Chakravarti and welcome back to Crash Course Organic Chemistry! What do Saturn, a diamond, and Giant’s Causeway in Ireland all have in common? Hexagons. From honeycombs to the shells of tortoises, hexagons ... Read More

Questions & Answers

Q: Why are hexagons so prevalent in the natural world?

Hexagons have a space-saving structure, making them ideal for packing objects efficiently. This is why they appear in structures like honeycombs and the arrangement of carbon atoms in diamond.

Q: How are cycloalkanes named?

Cycloalkanes are named based on the number of carbons in the ring, with the prefix "cyclo-" added before the root name. If there are substituents, they are numbered to give the lowest possible numbers, and arranged alphabetically.

Q: What is the chair conformation of cyclohexane?

The chair conformation is a puckered structure of cyclohexane where all the hydrogens are staggered and the bond angles are approximately 109.5 degrees. It is the most stable conformation due to its low ring strain.

Q: How do substituents affect the conformation of cyclohexane?

Substituents can be in either axial or equatorial positions in cyclohexane. In general, bulky substituents prefer to be in the equatorial position to avoid steric hindrance and reduce diaxial strain.

Summary & Key Takeaways

• Hexagons appear in various natural structures, such as Saturn, diamonds, and honeycombs, due to their space-saving properties.

• Cycloalkanes, including cyclohexane, are named based on the number and arrangement of substituents attached to the ring.

• Cyclohexane can adopt a chair conformation, which is the most stable structure due to its low ring strain.